1. Temperature Scales
2. Thermal Expansion
Expansion coefficient ratio (isotropic solid)
3. Calorimetry
Specific heat
Molar specific heat . Water: .
Principle of calorimetry
Insulated mixture, no heat escapes to surroundings.
4. Change of State and Latent Heat
For water at 1 atm: (fusion, at 0°C), (vaporisation, at 100°C).
- Melting plateau (0°C): temperature flat — all heat breaks bonds, none raises KE.
- Boiling plateau (100°C): flat again, but far WIDER than the melting plateau — for the same mass.
5. Conduction
Steady-state conduction
= thermal conductivity, W/(m·K). Thermal resistance , so (Ohm’s-law analogy).
Series slabs
6. Convection
- Natural convection: heated fluid expands, rises; cooler fluid sinks — sets up its own circulating current (land/sea breeze, boiling pot, weather).
- Forced convection: fluid pushed mechanically (fan, pump) — car radiator, blood circulation.
7. Radiation
Stefan–Boltzmann law (black body)
. Doubling absolute temperature multiplies radiated power by 16.
8. Newton's Law of Cooling
Newton's law of cooling
Linear approximation of radiative loss, valid only for small excess over surroundings . For large excess, true behaviour makes cooling faster than this predicts.
Full derivations and worked examples: detailed notes →
