1. Energy Bands
- Conductors: conduction and valence bands overlap, free carriers always available.
- Insulators: large gap (Eg ≳ 3 eV), thermal energy can’t bridge it.
- Semiconductors: small gap ( eV; Si ≈ 1.1 eV), thermally bridgeable, carrier count rises with T.
2. Doping
- n-type: pentavalent (donor) impurity, e.g. P, As — free electrons are the majority carriers.
- p-type: trivalent (acceptor) impurity, e.g. B, Al — holes are the majority carriers.
3. p-n Junction & Depletion Region
Diffusion across the junction leaves fixed ionised donor/acceptor atoms behind, a carrier-free depletion region with its own built-in field, which halts further diffusion at equilibrium.
4. Forward vs Reverse Bias — the exam trap
Diode equation
- Reverse bias: depletion region widens; current stays essentially flat at , no matter how reverse you go. V=−1 V and V=−5 V give the same current, non-Ohmic.
- Forward bias: depletion region narrows; past ≈0.5–0.7 V, current explodes exponentially. V=0.5 V → 0.2248 mA; V=0.6 V → 10.52 mA; V=0.7 V → 0.4927 A. Each +0.1 V multiplies current by ≈47×.
See it live: interactive diode I-V simulation →
5. Rectification
Half-wave rectifier: a diode passes only the half-cycle that forward-biases it, blocking the reverse half-cycle, converting AC into a one-directional, pulsing output.
6. Special-Purpose Diodes
- Zener diode: operated in reverse breakdown at a fixed voltage — used for voltage regulation.
- LED: forward-biased junction emits light on carrier recombination.
- Photodiode: reverse-biased; light increases reverse current — used to detect light.
- Solar cell: unbiased junction; light generates its own usable voltage and current.
Full derivations and worked examples: detailed notes →
